Vernier-Templated Synthesis, Crystal Structure, and Supramolecular Chemistry of a 12-Porphyrin Nanoring

Vernier-Templated Synthesis, Crystal Structure, and Supramolecular Chemistry of a 12-Porphyrin Nanoring

Vernier templating exploits a mismatch between the number of binding sites in a template and a reactant to direct the formation of a product that is large enough to bind several template units. Here, we present a detailed study of the Vernier-templated synthesis of a 12-porphyrin nanoring. NMR and small-angle X-ray scattering (SAXS) analyses show that Vernier complexes are formed as intermediat...

Supramolecular Chirality in Porphyrin Chemistry

Supramolecular chirality, being an intelligent combination of supramolecular chemistry and chiral science, plays a decisive role in the functioning of various natural assemblies and has attracted much attention from the scientific community, due to different applications in modern technologies, medicine, pharmacology, catalysis and biomimetic research. Porphyrin molecules are of particular inte...

Templated Fabrication of Nanowire and Nanoring Arrays

Synthesis and Crystal Structure of 5,10,15,20-Tetrakis(3,5-dinitrophenyl)porphyrin

The synthesis, characterization and crystal structure of the octanitro-substituted porphyrin 5,10,15,20-tetrakis(3,5-dinitrophenyl)porphyrin, H2T(3,5-DNP)P, are described. The solid state structure has two porphyrins in the unit cell with eight pyridine solvates and is made up from columnar arrays of the porphyrins. X-ray crystal structure data: monoclinic, space group P1 21/n1, a = 14.9996(9) ...

SYNTHESIS AND CRYSTAL STRUCTURE OF [Pph ] [WS (CUNCS) ] A. Taeb A. Beheshti and N.K. Javadi SYNTHESIS AND CRYSTAL STRUCTURE OF [Pph ] [WS (CUNCS) ]

The crystals of [WS (CuNCS) ] anion have been isolated from CH ,CI solution and examined by X-ray structural analysis as well as by IR spectroscopy. The unit cell is monoclinic with a= 14.3796(13), b= 18.039(1 I), c= 22.5956(23)& P= 96.053(8)', space group P2,/n (14), Z= 4. The crystal structure was refined by the least-squares calculations to a final R-value of 0.0398(Rw= 0.0443) for 2777 u...